2022AP環(huán)科手冊5/5 Pollution
Pollution Type
Air pollution 空氣污染∶
Primary air pollutants are released directly from their source into the atmosphere?
Secondary air pollutants form as the products of chemical reactions
Stationary source: e.g. factories or power plants?
Moving source: e.g. cars
Point source pollution: a specific location from which pollution is released?
Non-point source pollution: a combination of many sources that produce pollution
空氣污染物
CO: primary pollutant, incomplete fossil fuel combustion
NO2: primary pollutant, fossil fuel combustion; NO forms first,and is oxidized to NO2?
SO3: primary pollutant, the combustion of coal; SO2 forms first, and is oxidized to SO3?
O3: secondary pollutant, photochemical smog
PM 10: primary pollutants; particulates can be removed by filters or electrostatic precipitator Lead(Pb): primary pollutant, combustion of leaded gasoline and the peeling of lead-based paint
PANs: secondary pollutant, hydrocarbons+O2+NO2+light →CH3COOONO2(PANs); damage vegetation
Industrial smog (gray smog)灰霾
When CO and CO2 are released in the process of combustion, they combine with particulate matter in the atmosphere and produce smog.
SO2 may be another component in gray smog
Photochemical smog (brown smog)光化學(xué)煙霧∶
Warm, arid climates and lots of cars have the most photochemical smog NO2+VOCs+O2+UV→O3+ PANs
VOC∶ 揮發(fā)性有機物
Thermal pollution∶heat island effect 熱島效應(yīng)
城市暖氣流上升,郊外冷氣流下沉
城市內(nèi)的氣溫升高,降水量也增多(溫暖的氣體可以保存更多的水蒸氣)
影響∶
High levels of pollution in metropolitans?
Produce secondary effects on local meteorology
Temperature inversions 逆溫
溫度有可能隨海拔的升高而升高
When a laver of warm air sits atop cooler polluted air over a city and prevents the cool air from rising and dispersing its pollutants
Common over cities that are built in valleys or surrounded by mountains
影響:
Trap pollutants or cause other pollution
Acid rain 酸雨
酸沉降∶dry acid particle deposition & wet deposition(acid precipitation)
硫和氮的氧化物和水反應(yīng)形成酸,隨后形成酸沉降。氧化鈣、碳酸鈣等緩沖物可以減緩酸沉降的危害。
酸雨的形成
SO2+H2O→H2SO3 & 2H2SO3+O2→H2SO4?
2NO+O2→NO2 & 2NO2+H2O→HNO3+HNO2
影響∶
Damage of trees
Unhealthy for decomposers and mycorrhizal fungi?
Decay of building materials and paints
Lowering the pH of water, which may lead to fish kills
Lime (CaO) and limestone (CaCO3) serve as buffers that neutralize acids, and can be added to soils to reduce the effects of acid deposition
Indoor air pollution 室內(nèi)空氣污染
污染物∶ CH2O, C6H6, NH3, radon (Rn), tobacco smoke, certain living organisms?
Most abundant indoor pollutants: volatile organic compounds (VOCs)
提高空氣質(zhì)量的措施∶
Emphasizing tax incentives for pollution control?
Setting legislative standards for energy efficiency?
Increasing funding for research on renewable energy?
Incorporating incentives for reducing air pollution
Reducing the use of coal and firewood in developing countries?
Providing incentives to use mass transit?
Phasing out two-cycle gasoline engines
與空氣污染的相關(guān)法案
Clean Air Act: establishes national standards for the allovvable outdoor concentration of six criteria air pollutants to protect human health.
Noise pollution 噪音污染
來源∶
Wind farms > interfere local wildlife
Sonar > ?interfere migratory routes of marine mammals?
Airports, construction equipment, motorcycles, etc.
控制噪聲污染的措施∶
Use noise barriers, limit car speeds, control traffic flow → roadway noise?
Develop quieter jet engines, reschedule takeoff and landing time → aircraft noise?
Develop new technologies, install noise barriers →industrial noise
Control noisy equipment (e.g. power tools, loud radios)through laws and enforcement →residential noise
與噪聲污染的相關(guān)法案∶
U.S. Noise Control Act: establishes federal noise emissions standards, provides information to the public?
Quiet Communities Act: provides for the coordination of federal research and activities into noise control
Water pollution 水污染
來源∶
Excess nutrients (nitrogen, phosphate, etc.?)
Organic waste
Toxic waste (pesticides, petroleum products, heavy metals, arsenic, cyanide, acids)
Sediments (soil washed with runoff water into streams)
Hot water(discharged from industrial facilities where it was used as a coolant)
Cold water(from dam releases discharging it from the bottom of reservoir)
Coliform bacteria(bacteria found in the intestines of animals that indicate the presence of fecal matter in water)
Invasive species (e.g. zebra mussels)
Thermal pollution
水質(zhì)監(jiān)測的指標∶
Temperature: impacts the solubility of oxygen and the range of tolerance of aquatic organisms?
River/stream flow velocity: fast-flowing water can diffuse oxygen faster than slower-flowing water?
Turbidity: measure of the cloudiness of aquatic systems by suspended solids?
pH: normal for water is 6-8
Dissolved oxygen: amount of oxygen available in the water?
Nitrates and phosphates: nutrients and limiting factors?
Hardness: tests the presence of Mg2+ and Ca2+
Fecal coliform: determines the fecal contamination
BOD: a measure of the rate at which bacteria absorb O from the water
Eutrophication 富營養(yǎng)化
Excess phosphates and nitrates cause large algal blooms, which blocks incoming solar radiation?
Hypoxic zone:lack of oxygen; nothing that depends on oxygen can grow
控制富營養(yǎng)化∶
Controlling the use of fertilizer?
Controlling runoff from feedlots
Converting nitrates into nitrogen gas by denitrifying bacteria?
Absorption of nutrients by planning vegetation
廢水凈化∶
Primary treatment: physical process, reducing debris through sand catcher, screens, and sedimentation?
Secondary treatment: biological process, reducing biodegradable waste through filter and sludge processor?
Tertiary treatment: raising the effluent quality to the required standard through sand and carbon filters, and then further chlorination
與水污染相關(guān)的法案∶
Clean Water Act: use regulatory and non-regulatory tools to protect all surface waters in the U.S.?
Water Quality Act: encourages the separation of storm water and sewer water lines
Safe Drinking Water Act: requires the U.S.EPA to set standards of maximum containment levels for water pollutants that have negative health impacts for humans
Solid waste 固體廢棄物
來源∶
Industrial solid wastes: most come from mining activities?
Municipal solid wastes: trash or garbage thrown out by residents
Leachate 滲濾液∶有毒化學(xué)物質(zhì)泄漏,會污染地下水
Open dumps: large fields or holes in the ground, forbidden in most developed countries Sanitary landfills: more than half of municipal solid waste in the U.S.is buried in sanitary landfills?
Incineration: reduce the volume, waste-to-energy incinerators
"3R"處理固體廢棄物∶
Reduce 減少消耗∶
Reduce the consumption of consumer products and energy, requiring less raw material e.g. walk, bike, e-books, second-hand items
Reuse 重復(fù)使用
Reuse materials rather than relying on the production of one-time use items. e.g. cloth grocery bags, rechargeable batteries
Disadvantage: only when items are expensive and labor is cheap is reuse economical
Recycle 回收利用
Recycle materials to provide materials for new products.?
The U.S.currently recycles 25%-30% municipal solid waste e.g. plastics, paper, metal, glass
Disadvantage: poor regulation, fluctuation in market price, throwaway packaging is more popular
Human Health
需要知道的幾個有關(guān)術(shù)語
Toxicity 毒性∶ varies with the dose and may have a threshold level
Acute effect 急性效應(yīng)∶ immediate response
Chronic effect 慢性效應(yīng)∶long-lasting or permanent damage
Dose-response curve 劑量反映曲線∶an organism's negative response to the dose received
LDs0(median lethal dosage)半數(shù)致死劑量∶the dose required to be lethal for 50%of the test population
Non-threshold dose-response 非閾值劑量反應(yīng)∶the response begins at zero and increases with dosage
Threshold dose-response 閾值劑量反應(yīng)∶the response do not begin until the dose exceeds a threshold
Infection: the result of a pathogen invading human body?
Disease: when the infection causes a change in the state of health
Pathogen: viruses, bacteria, fungi, protozoa, parasitic worms
對人類有害的化學(xué)物質(zhì)∶
Carcinogens 致癌物∶cause or promote various types of cancer
Mutagens 誘變劑∶promotes mutations or changes in DNA; may also cause cancers or be pass on to future generations
Teratogens 致畸劑∶ cause birth defects
Neurotoxins 神經(jīng)毒素∶ cause damage to the brain, nerves, or spinal cord
Hormonally active agents (HAA) or endocrine disruptors: mimic estrogen or block androgens from binding to their receptor sites
對環(huán)境有害的化學(xué)物質(zhì)∶
Hazardous waste: toxic, corrosive, flammable, or dangerously chemically reactive
Developed countries are responsible for the large majority of the hazardous waste produced worldwide
相關(guān)法案∶
RCRA: EPA issues permits to companies that develop a plan for hazardous waste from the initial generation of the waste to the end disposal
CERCLA(Superfund Act): identifies areas that have been contaminated; these areas, known as superfund sites, are placed on the national priorities list for cleanup.
Basel Convention: requires the permission of developing countries before shipments of hazardous waste
有害物質(zhì)的處理
Bioremediation 生物治理∶ the use of organisms
Phytoremediation植物修復(fù)∶ the use of natural plants or genetically engineered plants
Incineration 焚化∶ creates toxic ash
Plasma arc torch 電弧焊矩∶expensive,produces carbon dioxide and releases toxic metals and radioactive elements
Deep-well disposal (injection)深井灌注∶ storing liquid hazardous waste;waste is pumped through pipes into permeable injection zones
Surface impoundment 地表蓄水∶storing liquid hazardous waste; waste lagoons lack adequate liners and leach toxins into groundwater
Hazardous waste landfill 填理∶ places waste in drums or barrels
Waste-to-Energy program (WTE)∶將焚化有害物質(zhì)生成的能量轉(zhuǎn)化為電能
污染造成的經(jīng)濟影響∶
Cost/benefit analysis: determine the best course of action
成本效益分析可以用于估測政策改變、構(gòu)想常規(guī)方案
Externalities(external costs)外部性∶any negative effects on the environment or society that are not included in the market price
Marginal cost 邊際成本∶in pollution cleanup,it refers to the cost of cleaning up each successive unit of pollution; generally it rises exponentially
Sustainability 可持續(xù)發(fā)展
Renewable sources 可再生資源∶often depleted due to unsustainable use(timber, fertile soil,and fisheries)
Nonrenewable sources不可再生資源∶deplete at a rate that is slow enough to allow their reserves to last for hundreds of years
可持續(xù)發(fā)展關(guān)注的問題∶
Consideration of risk, uncertainty, and irreversibility
Ensuring appropriate valuation, appreciation, and restoration of nature
Integration of environmental, social, and economical goals in policies and activities?
Equal opportunity and community participation?
Conservation of biodiversity and ecological integrity?
Continuous improvement?
The need for good governance